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Beilstein J. Org. Chem. 2007, 3, No. 33, doi:10.1186/1860-5397-3-33
Graphical Abstract
Scheme 1: Desymmetrisation of N-trialkylsilyldimethylsulfoximines using chiral bases
Scheme 2: Preparation of N-trialkylsilyl dimethyl sulfoximine derivatives
Figure 1: The diamine (-)-sparteine and three chiral lithium amide bases.
Scheme 3: Preparation of vinyl sulfoximines
Figure 2: Selected NMR Characteristics of sulfoximine amides 12, 13 and 14.
Scheme 4: Preparation of O-methyl mandelamide derivatives (S,R)-12 and (R,R)-12
Scheme 5: The influence of (S,S)-bis(1-phenylethyl)amine on the ee of 1b